Quadrupole Ordering and Rattling in Clathrate Compound Pr3Pd20Ge6
نویسندگان
چکیده
منابع مشابه
Quadrupole Order in Clathrate Compound Pr3Pd20Si6
In order to investigate ordered phases revealed at low temperatures in clathrate compound Pr3Pd20Si6, we have performed ultrasonic measurements using a single crystal in magnetic fields at low temperatures. Temperature dependence of elastic constant C11 and CL[11̄0] = (C11 + C12 + 2C44)/2 shows the anomalies at about 150 mK in zero field. Magnetic phase diagrams are determined by measuring C11 i...
متن کاملRattling ‘‘guest’’ impurities in Si and Ge clathrate semiconductors
In addition to their ground state, diamond structure, Si, Ge and Sn can form crystalline solids called clathrates. As in the diamond structure, in the clathrates, the Group IV atoms are tetrahedrally coordinated and sp covalently bonded to their neighbors. However, the clathrates contain pentagonal atomic rings and have open-framework lattices containing 20-, 24and 28-atom ‘‘cages’’. There are ...
متن کاملNMR relaxation and rattling phonons in the type-I Ba8Ga16Sn30 clathrate
Atomic motion of guest atoms inside semiconducting clathrate cages is considered an important source for glasslike thermal behavior. 69Ga and 71Ga nuclear magnetic resonance studies on type I Ba8Ga16Sn30 show a clear low-temperature relaxation peak attributed to the influence of Ba rattling dynamics on the framework-atom resonance, with a quadrupolar relaxation mechanism as the leading contribu...
متن کاملRattling guest atoms in Si, Ge, and Sn-based type-II clathrate materials
We have studied the vibrational properties of some of the compounds based on the Type II silicon, germanium, and tin-based clathrate materials using LDA electronic structure methods. The lattices in these framework materials have open cages which can contain weakly bound guest impurities, and these guests produce local (“rattling”) vibrational modes. Such modes may scatter the extended, heat ca...
متن کاملCrystal structure of melanophlogite, a natural clathrate compound of silica**
The high temperature form of melanophlogite, 46 Si02. 6M14 .2M12(M12=CH4, N2; M14=C02, N2), is cubic with space group Pm3n and a = 13.436(3) A at 200°C. The mineral is isostructural with the cubic gas hydrates of type I. Structure refinement with 667 independent reflections led to a weighted Rw = 0.040. Corner-sharing [Si04] tetrahedra form a 3dimensional framework which contains two types of c...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Physics: Conference Series
سال: 2011
ISSN: 1742-6596
DOI: 10.1088/1742-6596/273/1/012002